India's Ravinder Khatri went out of the Greco-Roman 85kg category after suffering a first round loss on Monday in Rio de Janeiro.
He lost to Viktor Lorincz of Hungary and bowed out of the competition.
The 24-year-old lost 9-0 on Great Superiority. Great Superiority indicates a difference of eight technical points in Greco-Roman with the loser not logging any points.
Khatri gained an Olympic berth after Kenzheev Zhanarbek of Kyrgyzstan failed a dope test in the Asian Olympic qualifier in Kazakhstan.
This is the first time that two Indian Greco-Roman wrestlers have secured Olympic quotas after the 2004 Athens Games when Mausam Khatri had made the cut.
Khatri's early elimination has left only compatriot Hardeep Singh (98kg) in fray in the Greco Roman category.
Hardeep will be seen in action on Tuesday.